c6h5ch2

By Admin 18/09/2023 0

  • Formula: C7H7-
  • Molecular weight: 91.1310
  • CAS Registry Number: 18860-15-6
  • Information on this page:
    • Vibrational and/or electronic energy levels
    • References
    • Notes
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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 7360 ± 50 gas Gunion, Gilles, et al., 1992
Kim, Wenthold, et al., 1999

State:   ?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
945 gas PD Wight and Beauchamp, 1989

State:   ?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
514 ± 15 gas PE Kim, Wenthold, et al., 1999

Additional references: Jacox, 1994, page 394; Jacox, 2003, page 373

Notes

dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Gunion, Gilles, et al., 1992
Gunion, R.F.; Gilles, M.K.; Polak, M.L.; Lineberger, W.C., Ultraviolet Photoelectron Spectroscopy of the Phenide, Benzyl, and Phenoxide Anions., Int. J. Mass Spectrom. Ion Proc., 1992, 117, 601, https://doi.org/10.1016/0168-1176(92)80115-H . [all data]

Kim, Wenthold, et al., 1999
Kim, J.B.; Wenthold, P..G.; Lineberger, W.C., Ultraviolet Photoelectron Spectroscopy of, J. Phys. Chem. A, 1999, 103, 50, 10833, https://doi.org/10.1021/jp992817o . [all data]

Wight and Beauchamp, 1989
Wight, C.A.; Beauchamp, J.L., Multiphoton electron detachment studies of C7H7- using a low-power infrared laser. Competition of radiative and collisional relaxation with vibrational excitation, Chem. Phys., 1989, 134, 2-3, 375, https://doi.org/10.1016/0301-0104(89)87169-1 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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  • Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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